What are you going to do with the information? Are you trying to see if the valve supplier conformed to the specified sound pressure levels? The supplier of the valve should be able to predict the sound pressure level one meter downstream, one meter away from the valve while flowing steam and supply that information to you.
For field measurements, I agree with Greg Locock on the sound intensity method. If you are able to remove the downstream insulation, and the plant operator can run through some varying pressure conditions and valve travels (which are big ifs), you would be able to get some good information using sound intensity. Doing a noise survey of the area while certain valves are running, using sound intensity, would provide valuable information too. If you are able to get to the downstream pipewall, and use an accelerometer that can withstand the heat, you could take some pipewall vibration velocity response measurements and calculate the radiated sound pressure levels.