Coating of CS Fasteners is quite common along the Gulf Coast and getting more play in quite number of chemical companies. A lot of companies have standardized on Green or Blue Coatings for all CS fasteners above 1" temperatures permitting.
One problem we and others have run into is with CS/SS flanges in Class 150 especially in the 3" and 8" sizes.
We got into a big trap on several large projects where they used CS backup flanges for SS lines mating with SS flanges.
Just because it works on paper doesn't mean it works in the field, check around and see if your people have any experience in using the combination in certain areas as atmospherics are not the only problem as process can enter the picture.