If I understand the question correctly, you are asking if you can qualify welder and a WPS using API 5L Grade B and use API 5LX 70 for production welding. With the belief that you are usng ASME IX code, and although you did not specify the welding process:
1. You can qualify welders on Grade B and weld X70 for production.
2. If supplementary essential variables
DO NOT APPLY, you an use the Grade B WPS to weld API 5LX 70.
If supplementary essential variable
DO APPLY, you cannot use the Grade B WPS (P1 Group 1) to weld API 5LX 70(P1 Group 3) as a change in material group is a supplementary essential variable . See ASME IX QW-403.5.
If using API 1104, welders qualified on grade B can weld X70 (within other retrictions shown in Section 6). Again, for API 1104, a WPS qualified on Grade B is not acceptable to use to weld X70.