msugog -
The NCMA Tek Note 9-4A (ncma.org) give a very good summary of grout for masonry construction. This refers to ASTM 476 (and others) and ACI 530.
According to ASTM C476:
4.2 Grout proportions shall be determined by ONE of the following methods:
4.2.1 Requirements of Table 1.
<This will provide the proportions for a grout meeting the minimum 2000 psi strength requirements It generally states the fine aggregate should be be between 2 1/4 to 3 times the VOLUME of the cementitious materials. For coarse grout, coarse aggregate of 1 to 2 times the VOLUME of the cementitious materials may be added. Like most ASTM aggregate requirements, variations from gradation requirements may be permitted if a history of performance can be shown>
4.2.2 Specified Compressive Strength.
Proportions established by 28 day compressive strength tests in accordance with test method C1019 that obtained the specified compressive strength. The grout shall be mixed to a 8 to 11 inch slump.
<This is for verification of the 2000 psi or higher strengths if speified>
The specifications should require only one of the methods. It is the classic case of either requiring the proportions or requireing the performance.
The first is a conservative and simple "bullet-proof method to acheive the minimum 2000 psi strength with out excessive testing and complications. The second method is similar to a concrete mix design that is verified by site testing for compliance when higher strengths are required.
According to ACI, it is best to balance the specified grout strength with the specified concrete masonry assembly strength so one element is not considerably stronger than the other. ACI 530 also has a maximum limit of 5000 psi as the specified strength for grout, but stronger grout may be used if it tests above that strength. - This all is a means to provide a balanced design where one portion of the wall does not absorb an excessive amount of the load.
From a practical standpoint, 3000 psi f'm and grout is a very workable system. I have had 4500+ psi f'm hollow prisms made (8000 psi block), but you would have to have some very unique loads and conditions to require this level of strength. Also, you may not be able to find a testing laboratory with a testing machine with thick platens capable of testing a 16" high sample with that much area.
Just as a starting point, a fine aggregate equal to 2 times the cement volume would give you about 3000+ psi grout, depending on the fineness.