dhiggins:
Good question.
Article 347 states that you can have rigid nonmetalic conduit up to 6". Article 351 as you say states that the maximum for liquidtight flex is 4".
I had 6" flex in my mill that was grandfathered all the way into the early 80's. I can see what I can find out for you, but as code stands, new installations of 6" flex is not code compliant.
Carl