Yes, ASME B16.47 is almost always used for flanges that exceed the ASME B16.5 size range. In general, one would use Series B, which is equivalent to the old API 605 bolting dimensions. However, if you know that a flanged valve is going to be bolted directly to one of the vessel nozzles, you want to use Series A, which is based on MSS-SP-44 bolting dimensions.
If your vessel is to be installed in an existing plant facility, it is a wise practice to check the attached piping flanges to make sure you have the correct type and bolting dimensions. There could be an existing pipe with an "Appendix 2" flange, or a manufacturer's standard flange that doesn't match either Series A or B. If this is the case, you want to find that out immediately to prevent a potential embarrasing situation.