A typical grout height for a 56" diameter stack would be 1 inch. The grout is intended to allow more exact trueing/ plumbing of the stack and more accurate placement at the design base elevation. As you get larger in diameter, and the potential variability of the top of concrete increases, a greater height of grout can be considered. In line with Ginger's advice the plumbing and elevation setting is done with the shims. After that is completed, grouting to fully support the stack base plate is performed.