belfour30;
Because the maximum working pressure for a Class 150 flange for this material group is only 25 psig and that is at 1000 deg F, regardless if it is solution annealed. If you go higher in service temperature, you will have significant creep deformation and subsequent leaks with this flange, because the flange is not adequately reinforced.
Why don't you go to a Class 300 flange for N08800 and be done with it? At 1500 deg F, a Class 300 flange has a working pressure of 25 psig.