There has been a lot of experience with hydrogen by Nasa, and in large power plants where the electric generator is larger than 250 MWe. There have been fires and explosions related to hydrogen leaks, but following basic guidelines has led to a managable use of hydrogen in those industries that have a trained workforce.
Straightforward guidelines can be found in Nasa's Safety Standard for Hydrogen and Hydrogen systems NSS 1740.16 <
However, ignoring the special safety requirements , or use by untrained consumers, can lead to fires and explosions. Major fires and explosions had occurred at some Nasa rocket sites, and also had occurred at some large electric utilities , when the guidelines were not followed.
H2 will leak out of flanges, threaded fittings ,valve seats , and faulty welds. Upon leakage to the atmosphere it will ignite nearly spontaneaously , as it has a very low energy of ignition requirement; a simple particle of rust impinging on a pipe is enough to spark a fire or explosion. The H2 fire is nearly invisible, and early efforts to determine the location of a H2 fire ( by "rocket scientists" ) included waving a straw broom ahead of the operator as he walks around , or throwing a handful of sawdust in the air ahead of the operator.
Nasa recommends the H2 transport pipe be the highest pipe in the pipe rack, and never to route H2 pipes underground, as a leak ( caused by corrosion) will cause H2 to leak into unpressurized drainage pipes in the vicinity , and just flushing a toilet can lead to a sewer explosion.
"...when logic, and proportion, have fallen, sloppy dead..." Grace Slick