Here is a few other ideas. You have me stumped. I have used the alloy many times, from small diameter sch 5 pipe up through 12" sch 120 pipe without problems except for the occasional crater crack.
- Nickel Oxide is black in color. Could the welder be using too much Gas and creating turbulence, hence pulling oxygen into the weld pool?
- Does the Black material react to Nitric acid? (Check for Iron)
- Have you carefully ground out the defect. Is it all on the surface is dispersed throughout?
- If you can get a sample of the black material is it magnetic?
- Take a sample of the black material and put in in a small vial add household ammonia (small amount), shake, doe the ammonia change color? what color? If it turns blue (Royal Blue)it is probally a copper compound.
I wish I had a better answer. It concerns me that it is forming in the weld puddle.
Rich