The optimum pitch claim from CAT came from the days when their EPG business was mostly SCR drives for drill rigs, and in those days the CAT tail ends were hard to beat, and the 4/6 pitch was very good for the 6 pulse drives found in the field. When the SR4 tail end came out it was available mainly in 4/5 pitch, and many units were shipped 5/6 pitch as well, again targeting the drilling and single unit industrial markets. Now most of CAT's tail ends are 2/3 pitch, a quiet shift over the years. The other pitches are still available, but mostly as special order.
We have paralleled a number of non-2/3 pitch machines with both the utility and other machines of different pitch, usually requires a neutral grounding reactor installed.
There have been more than a couple of times when an expansion or new project forgot to take that issue into consideration. Most of the local engineers I deal with where I live are famiilar with DG know the issues and account for them. But quite a few people aren't and it can cause some headaches, everything from complete unit changeouts to floating neutrals, depends on the site and application.
Cummins and Marathon also have excellent papers on generator winding pitch, the current Cummins info is probably the most up to date of any of the US manufacturers I know of.
Hope that helps