I agree with all waross said and add the following:
The sparking and burning on the commutator of the DC Exciters is most likely the cause of the subsequent sparking on the slip-ring brushes.
DC Exciters operating correctly will provide a smooth DC current to the excitation slip-rings of the generator.
Check the DC waveform being generated on an oscilloscope.
Burnt commutators indicate DC Exciter issues (neutral, compole problems etc!... )resulting in deformation of the commutators and poor quality DC to the generator.
There are modern instruments available to measure commutator deformation with both contact and non-contact methods.
Smooth it all out.
RD