Both type of flanges the Raised Face and the Ring Joint flanges can be refaced. The only thing is that you have to watch out for overlay on some flanges in H2S service. The was a lot discussion about weld buildup and machining of flanges in H2 service, The information I have is if the proper electrode is used there is not problem.
The problem with RTJ Flanges is that they aren't many machines out there and usually the refacing is done by speciality contractors. I've seen several jobs where the people claimed the ability to reface RTJ's Flanges but in the end they failed miserably. We took the approach that it was the last resort to face a RTJ Flange. We have literally thousands of 3/4"-2" RTJ Flanges that get made up at least one and possibly 10 times a year, so we watch these closely as we don't machine on these we replace the flange, it's cheaper. There is a set of gauges for RTJ Flanges that will help you decide the condition of the seating surfaces.
One thing you can do is rent the tools to machine the Raised Face Flanges. This works out depending on the number of flanges and whether you want a contractor to come in.
On the Raised Face Flange, especially in our jacketed polymer piping system we routinely machine them. We have the in house capability of field machining up to 96" OD flanges. As I mentioned above we will back spot face the bolt hole, which is done more often than refacing.