Molten iron drops (you don't actually specify the metal or the temperature of the drops) will still ignite flame retardant plastics, but the fire will quickly self extinguish. The wheel will still be damaged a little each time and pieces of metal will get stuck in the rolling surface making it difficult to roll.
I still stick by the cast iron recommendation, or possibly aluminium. Either metal with a replaceable FR rubber tyre might work. I am not up on FR rubber, but I am sure there will be good knowledge available on the DuPont web site, or whatever Bayer's rubber division is now called.
If it has to be plastic, FR nylon, once again, possibly with a replaceable rubber tyre. Wether or not you can buy FR nylon castors is another story. Although you don't say, I am presuming you do not require enough to warrant setting up a production run in a special grade.
The flame retardant spec most relevant to your application should be the glow wire test.
Regards
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