First thoughts are to use a coating on the SS to remove the friction of the sides. Sprays, CVD, MVD, plating, liners, etc. of slick polymers, PTFE, esters, silicones, PVC, etc. are possibilities.
But, there are many more questions to address. Is this a powder or just real small granules? Is the problem it sticks and then bridges over to where the middle will not drop? This then requires asking if you have tried vibrators, or spurge rings/air wash-stirring, what it the diameter of the silo, what is the angle of the sides, are the sides straight or do you have a spiral discharge, etc.? Can you apply, install a surface yourself or can you send the silo out for a factory install process?