There are significant construction differences as well. MCCs use removeable "buckets" for motor controllers up to a certain size (NEMA size 4 or 100HP @ 460V) that stab into the bus bars for quick replacement. They can have "feeder breakers" as well and they are also usually in buckets up to 250A frames. Switchgear, on the otherhand, generally does not contain motor controls in low-voltage systems and the breakers are not required to be removeable using stab-in connections. They also fall under different UL testing classifications as well. LV Switchgear is usually UL1558, MCCs are UL485
Once you get into Medium Voltage the differences tend to blur. Then again, the definition of Switchgear gets more complicated as well, i.e. Metal Clad or Metal Enclosed, Load Interrupter or Arc-Proof etc. In MV systems, especially Metal clad, motor control is often mixed in with "Switchgear" because it is often too expensive to have separate systems and the number of MV motor controllers is usually relatively small.
"Venditori de oleum-vipera non vigere excordis populi"