Stanier,
No. It's left up to the judgement of the PE to determine what s/he is qualified to do or not. As B31.3 lists its experience requirements, supposedly a licensed PE would adhere to those prerequisites. A P.E. would be subject to a complaint, hearing with the state engineering license board and a possible loss of licensure, a malpractice suit in civil court, or even criminal malpractice and prossecution, in the event of serious mishap.
dantalbot, Yes it is the same state boards that oversee PE licensure and subsequent practice. An engineer, or an engineering company, must have a license to practice as an engineer, a company by virtue of having a licensed engineer qualified in the discipline(s) they work in as a member of their staff. Certain projects, especially those falling somewhere within the public domain, federal, state and local government sponsored projects, although that is extended by further requlation into many private sectors, are mandated by law to allow only PEs to certify the validity of any engineering work carried out for them.
From "BigInch's Extremely simple theory of everything."