ajk1....assuming the delamination is somewhat above the bottom of the slab, if you drill into but not through the slab, you'll likely intersect the delamination. If you pour water in the hole and get a rapid loss of water, you've found a delamination. Make sure no one is standing around the hole when you do this....you don't want the delamination compressed.
You can also seal a clear tube above the hole and pour the water into the hole and up the tube. It allows you to better see the water column fall, if it does.
Not foolproof, but can work.
As for the GPR, we have tried to build numerous calibration sections to check such things. We have built a wall behind our office with a variety of different conditions of lack of continuity of sections, various rebar locations, voids, etc. Our GPR picks up lots of things, but unless there is a clear air gap, it won't show.