Thanks for re-uploading in historic format...
After looking at the data, the first thing I would do is try to get a better view of the relevant information. The curve/data for compression simulation can be removed since you have no values to compare it to. Similarily, the experimental data with strain greater than about .007 can be removed, since you don't have simulation for comparison. Enlarge the graph a little and the difference between the curves is much easier to see than with all the irrelevant data included. This still does not give you meaningful mathematical comparison, but just makes the curves easier to view.
The other thing is that there are two distinct ranges that exhibit different behavior. This is expected as you are obviously looking at the elastic and plastic regions. I would divide each set of data into two ranges and try to fit a curve to only the range you are interested in. For example, I removed all the data with strain values less than 0.1. Fitting a exponential trendline to the remaining data for each set gave a pretty nice fit.
To add a trendline, right click the data on the graph, and select "Add trendline". A window will appear asking for the type. As I said, I tried an exponential curve. Then, select the "options" tab and put a check mark in "Display equation on chart" and "Display R2 value".
With all of the above steps, I was able to get the following information for strain ranging from ~0.1 to ~0.7:
Experimental: 13.607e^.970x
Simulation: 13.660e^1.023x
("x" indicates the strain)
The R2 value for both curves was <0.998
Using the equations to approximate each curve, I plugged in a test value for strain (0.20) and received stress values that differed by approximatly 0.24. At a strain of 0.68 (at the left side of the chart, where the trendlines are clearly farther apart, I got a difference of about 1.07.
I hope you followed what I have done and it provides some help. If this is not what you are looking for or you need a more accurate or descriptive analysis, I think you will need to find a good statistics book or similar.
-- MechEng2005