The “real” NEC limit is placed on the conductors not the “raceway.” See the NEC definition of “raceway” which includes, but isn’t limited to, all the conduit forms is Chapter 3. See also Section 310.13 and it’s limitations applied to conductors listed in Tables 310.13, 310.61, 310.62, 310.63, and 310.64.
Other conductors, say those in Art 725, and not listed in Tables 310.13, 310.61, 310.62, 310.63, and 310.64, may possibly be used in the tube without additional requirements. Since I don’t know the full scope of your applications this is the best info I can give at the moment.