I did a lot of wood fired, stoker type, fixed grate, and traveling grate boilers many years ago when I was just a pup, and I noticed from plant to plant that the plywood plants, burning the same basic bark, sawdust and wood trim waste that a sawmill down the road (sometimes same company, same boiler types, etc) was burning, that the sawmills, paper mills, etc had minimal problems with clinkers on the grate; not that there weren't any, but just that they weren't huge issues.
The plywood plants on the other hand were such that the operators would have to take Bobcat skid steer type loaders and run cables into the furnace and "lasso" or hook the clinkers and try to jerk them hard enough to break them into smaller pieces small enough to be able to drag through the furnace clean out doors (about 18" wide). I've seen clinkers that had to be broken in several pieces before they could be dragged out of the furnace.
I always attributed that (my opinion only) to a combination of the amount of dry waste - burns hotter than wet waste - and something in the glue (phenolic compounds???) that acted to fuse the ash.
Many of the sawmill and paper mill boilers burnt dry waste with the wet bark and sawdust, but none had the problems of the plywood plants. And it was pretty universal among the plywood plants that I dealt with and that measured in the several of dozens.
RR ties are going to be dry waste to start with, and there may be something in the preservative chemicals that are cooked into the RR ties that is acting like the (supposed) glue in the plywood dry trim waste.
rmw