Yeah, you're probably not going to find a single chip that does what you want. The Maxim MAX660 will double a voltage (or generate an inverse) with a 100 mA load but is only specified down to 1.2 volts, not quite what you want. If that's good enough, and you only need 50 mA or so, you can cascade a couple of them.
What level of current are you dealing with? Size of capacitor?
There are plenty of circuits that can boost from 1 volt to several volts, but they generally use discrete parts.
If you really need to charge 4 caps in parallel and then connect them in series, I suggest using a low power boost circuit to generate enough voltage to power some MOS devices to do the switching. That way, you can tailor the devices to the power level you require.