Any CT with an iron core will saturate if the current is high enough - none are immune. If the available fault current is below the knee of the saturation curve, then that CT will not saturate in that particular application. The intended application and purpose of the ZSCT has to be considered. In most industrial applications, these are used on medium-voltage feeders. In many cases, there is no MV ground fault protection downstream of this feeder breaker, so ground fault protection can use instantaneous trip functions. For these applications, even if the CT may saturate, it doesn't do so instantly and the relay will most likely trip. If you are trying to coordinate three or four levels of ground overurrent protection and tripping times are long, then the ZSCT is probably not your best choice for sensing ground current. Generally though, industrial medium-voltage systems should not be solidly-grounded.