You need to copy the inner surfaces of the cavity into a new part.
In WF2: (The process is the same in 2001/WF, but the interface controls are not)
Select a surface inside the cavity (so that it is highlighted pink). Then, hold down shift and select the flat face of the mold. Release shift, and all of the surfaces inside the cavity should be selected. (This is the seed and boundary selection method. The first surface is the 'seed', and Pro/E selects all surfaces adjacent to one another, starting from the seed, until it hits the boundary, which is the second surface you chose).
While these surfaces are selected, copy and paste them into a copied surface feature. Then, you can use one of a few techniques (copy geoms, or straight copying and pasting in a ghost assembly) to copy the surface into a new part.
Finally, you will probably need to make a flat surface (Use Edit-->Fill) to close off the surfaces. Merge these together to form a closed quilt, and solidify them. You should now have a part which exactly matches the cavity geometry inside your mold!
Hope it works
Mark