Hi There,
It is not an easy question, and it involves many potential risks.
Reducing pressure of a boiler, for small differences in pressure, ceteris paribus, leads to little savings.
Reducing boiler pressure will result in lower temperature of the flue exhaust gas (burning fuel), hence there are some savings there (sensible heat lost in flue gas). As a thumb approx rule, you can say 1% overall energy efficiency in the boiler for every 22ºC reduced in the flue gas. Thus expect no more than a 0.2-0.3% boiler efficiency improvement from this effect (183ºC vs 178ºC - difference in steam, expect no big difference in flue gas temp).
Reducing pressure in the boiler will have as a direct consequence a reduction in the pressure of the steam in the pipelines all the way between the boiler itself and the PRVs. This might also mean slightly lower heat losses to the air from the pipes, again small difference (you can check the delta[deltaT]).
You must be very carefull no to reduce too much the pressure of the boiler, since the lower you run a boiler (pressure) the smaller the real capacity of the boiler, since being lower density the steam (higher speed through outlet of boiler); the chances of having extremly undesirable and damaging water carryover increase.
NOTE: from energy point of view, the enthalpy of 140psi steam and 125psi steam is essentially the same (aprox. 0.2% difference) ...
Hope it helps,
BR;
RTO