A window CT will register all of the current going through the window unless high current saturates the CT. With a cable or bus perfectly centered in the round window, all parts of the CT core are equidistant from the current conductor. With an angled conductor, parts of the core are closer and could become saturated more quickly than other portions during high currents. So, yes there is an effect but it is probably within the accuracy range of the CT.
The CT with angled bus will probably read very close to the ideal current.