You have to study the set of curves provided for the particular centrifugal pump to begin to understand what's going on, because centrifugal pumps' flow rate is not fixed relative to its rpm, like a piston pump. Even if the centrifugal has a nameplate that says 'X gpm', it will almost never run at that exact flowrate.
The easiest condition check you can do is install a compound vacuum/pressure gage between the discharge of the centrifugal pump and the suction of the piston pump. If the pressure stays above the NPSHR of the piston pump at all times, you don't have a problem.
If the inter-pump pressure goes below the NPSHR of the piston pump, then you need a bigger or faster or rebuilt supercharge pump, or you need to clear the clog from its inlet.
Also note that centrifugal pump curves are typically provided for water. If you're pumping something else, you need to correct the curves or the math. Check the detailed data sheets for the centrifugal pump, and look up 'affinity laws'.
Mike Halloran
Pembroke Pines, FL, USA