Well, the simple answer is that "Boiler operating pressure" is the pressure that you operate your boiler at. But I think you knew that. Beyond that it is a bit hard to help with the info that you have given.
I'm not familiar with bladder tanks used with steam, but if you need steam at 220F, let's see, that's a bit over 104C - heck 120kPa will give you that (17psig). But then there are losses to consider, so you need higher pressure to overcome those, and ensure you still have steam where you want it (and not just condensate). Also, the higher the pressure the smaller diameter pipe you can use to transport the steam.
If the data you have provided is for the "bladder tank"(?), then I'm not sure what the steam side conditions need to be - the temperature change is a start, but you need also flows to work out the heat required.