More informatino on your requirements would help in getting better suggestions.
Do you need continuous monitoring, or is once a month (day year, millisec?) good enough.
How accurate?
A switched circuit using relays would eliminate drain when you are not monitoring.
Relays may be low reliability, FET's may do.
A high Z bridge set to near whee you expect the voltage to be could be a very low drain (and possibly a charge instead of a drain) possibility.
Do you need to know the voltage, or do you need a trip point indicator? If all you need is a trip point, what latency can you afford? Within an hour or a few seconds?
Without further information a guess would be a timed relay to a beridge with an accurate monitor. This solution could be much more expensive than you need, so better requirements can produce more cost effective solutions.