StructuralEIT,
Take the civil PE exam in Fall 2010 to get your PE, then sit for the Structural exam the next spring.
As far as I understand, the new SE exam is to become licensed as an SE, not a PE. The new exam is only going to be mandatory for people in states that require licensure as an SE to do structural engineering. I really believe (and hope) that more states will require the exams in the future, but for now the more important thing is the PE license.
I'm in GA, and will be sitting for the PE exam this fall, and I do plan to take the new SE exam in 2011, but that's only because I really like structural engineering and studying for tests late into the night.