The Safety Relief Valve forum would have been a better place to ask this question. You may want to put a link in the PSV forum pointing to this question to see if you get some more support.
After sizing a PSV using real gas methods, one knows the flow area and coefficient that is required. If the vendor checks the sizing using ideal gas methods, and comes up with a different flow area/coefficient, then there needs to be a technical discussion with the vendor. In my experience, this difference due only to sizing methods is rare. The flow would have to be on the edge of the PSVs capacity for this to happen. I don't remember a single case where this has happened to me.
Good luck,
Latexman
Technically, the glass is always full - 1/2 air and 1/2 water.