What do you mean by the "elastic matrix (G)"? A stiffness matrix for a ply will have nine terms if it is a Q matrix.
If the XX, YY, ZZ, are just the direct ply stiffnesses in the X, Y and Z directions then XY is in-plane shear and YZ and ZX are out-of-plane shear. These are independent and must be measured. They can be (very) roughly estimated by micromechanics but cannot be deduced from the X, Y and Z properties.
See NASA Technical Memorandum 83696, "Simplified Composite Micromechanics Equations for Strength, Fracture Toughness, Impact Resistance and Environmental Effects" by C. C. Chamis. (Just googling for NASA TM 83696 should give a suitable ref.) You could also try NASA TM 2007-214673 "Composite Nanomechanics: A Mechanistic Properties Prediction".
Or you could try
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NASA RP 1351, "Basic Mechanics of Laminate Composite Plates", by A.T. Nettles, is also very useful.
From the look of it your X, Y and Z properties are for a unidirectional glass fiber/polymer composite (possibly a high fiber volume fraction of E-glass or a low volume fraction of S-glass). I'd expect the shears all to be about 4000 or 5000 MPa.