To answer your questions:
1) I've been involved with ammonia refrigeration since 1996, both as a design/build contractor and a year as an operator.
2)Ammonia is listed as a highly hazardous chemical due to its flammibility properties (which is rare) so in my book training is required. Legally very little is required in the United States at this time, and what is, is usually HAZWOPER training.
3)RETA,IIAR,Garden City Community College in Kansas?,Northwest Technical Institute in NW Arkansas,University of Wisconson, and the University of Ill. at Urbana had a course at one time. The schools offer a variety of courses, generally for system operators. IIAR and RETA offer books with RETA aimed more toward operation and IIAR toward design and installation. But these names give you a starting point for a web search.
4)Typically ammonia equipment manufacturers do not sell directly to the end users, they prefer to deal through ammonia refrigeration contactors. I will name off a few names:
Ammonia screw compressor packages are made by Frick Co.(part of York Intl) FES part of GEA, M & M Refrigeration, Mycom and Vilter. Mycom and Vilter also manufacture recip compressors. I've listed these alphabetically not out of my perferences. All of these companies maintain websites and market other components for ammonia refigeration systems.
Air cooling evaporators:Baltimoe Aircoil Co.(BAC), Evapco,Frick/Imeco,Frick/Frigidcoil,Krack
Valves(control and stop)Refrigerating Specialties part of Parker, Hansen,Danfoss/Danvalve,Sporlan
5)I don't know the actual numbers but in -40 degree(F) to +40 degree(F) with a load in excess of 100 tons in the poultry,pork,beef and a large number of storage freezers industry it will most likely be ammonia.
Most of the companies above have web site with information about their sales reps.,contractors and design firms they work with on a regular basis.
Ammonia refrigeration design and installation is a relatively narrow field, especially when compared to general mechanical contracting and HVAC work, and as rgoulet stated above "It takes some time to develop a reputation with NH3 but it can be a good part of any mechanical contractor's bag of tricks."
Unless you want to pay for someone's time to develop their reputation with your capital, in a specialized field use contractors that specialize in that field.