Parts of the following are taken from ASM Volume 6 Welding, Brazing, and Soldering:
The oxyfuel gas welding (OFW) process uses a flux and either an oxyacetylene or oxyhydrogen gas flame. When the oxyacetylene flame is used, a slightly reduced flame is required, which causes a carbonaceous deposit that obscures the weld and slows the travel speed. The visibility, control, and weld speed are obtained when an oxyhydrogen flame is used with aluminum alloys.
The flux is composed of fluorides and chlorides, and must be removed after welding to avoid corrosion in service. For this reason, GTAW has generally replaced OFW of aluminum alloys. The use of a flux limits the alloys for which it is suitable (basically only 1XXX, 3XXX, low solute 5XXX, and 6061/6063) and produces the greatest heat input. This results in the lowest mechanical properties and highest sensitivity to weld cracking with heat treatable aluminum alloys. The advantage of the OFW process is the low equipment investment.
Care must be taken in order to insure a reducing atmosphere, as oxygen uptake creates extremely brittle welds. It is extremely difficult to obtain a neutral oxyhydrogen flame by the visual methods of flame adjustment. The oxyhydrogen flame itself is scarcely visible, and no combustion zones, typical of the hydrocarbon gases, can be determined. To avoid an oxidizing flame, excess hydrogen must be present. Since there is no carbon in the gas, the temperature is several hundred degrees lower than a neutral flame. A ratio of 4:1 hydrogen to oxygen is typically used.