Nice to get the info eventually - next time when you ask a question please provide all the info in one go - it makes it much easier to rule out some of the questions we've been asking you.... you still haven't said what the material is though.
This is 7" NB pipe alright (7.625" OD). I have found the odd reference to 7" pipe in some catalogues, but when you click on further links it then disappears. I've never seen or heard of 7" pipe before so I'm all out of ideas.
I can only suggest you keep on searching and if possible see if you can talk to the operators, find an old design and talk to the designers or even a material certificate for the existing pipe buried in the plant archives. Try a few pipe stockists - even if they don't stock it they migth know of a vendor who would do "specials", but brace yourself for the price....
It shouldn't be up to you to find this on your own - you've looked hard (I hope), asked a few people and now you need to go to your supervisor, not the client as he doesn't sound very helpful, and tell him your story.
My motto: Learn something new every day
Also: There's usually a good reason why everyone does it that way