I'm a bit more risk-taking, so I think you should take the job. I'd only agree to do this job after receiving a lot of documentation about the testing and specifications. I'd imagine it uses fiber reinforcement or metal shards instead of rebar. I'm not too familiar with it, but last time I checked, there is an ACI code on this. I attended some webinar about alternatives to rebar, so there's research about it out there. Also, there should be some contingency about what happens if the construction fails to meet requirements.
The concrete itself should comply with compression strength testing using cylinders taken from the site. I don't think the bending needs to be tested. I'm not sure how one would test/inspect the fiber reinforcement, but the testing/inspection procedure for that should be noted as well. It might be on their ICC reports. I'd also look into things like how they test for slump, air content, and vibration during pouring/3D printing. Since this is a pretty new thing, I'd look deeply into every aspect of the design mix and how things are verified, and what the building department would be willing to accept as far as testing and specification.
Then there's the question of the limitations of the 3D printing. I know that regular 3D printing has limits on things that can be printed and even requires "formwork" for certain things. So all of that needs to be considered in the design. If it's just footings or piers, I wouldn't worry. But if it's a shear wall with openings or even a floor slab, I'd look into it.
I'm guessing they have their own engineers but would need an EOR in Jersey to sign off on things. So you have to do your homework and coordinate with the building officials. If New Jersey is anything like New York, the building departments vary from town to town, so you'd have to do it in multiple areas (possibly using one area's letter of acceptance to influence the others). Obviously, you charge the owner for all this legwork. But it's kind of a one shot deal for each building department.
From an entrepreneurial standpoint, I think your client is trying something bold. And if you pull it off, jerseyshore will be the go-to engineer for 3D printed concrete in your area.