I work In plastic bottle design, and creating a hollow model is a time consuming and usually not needed. For calculating internal volume (brimfull) our method is to determine the weight of the bottle material, and then using the material density calculate the material volume. Its then a simple matter of subtracting that volume from you model mass properties. For measuring volume at a specific fill point you usualy need to measure or estimate the material weight under that point then use a datum plane and one sided volume to calculate the volume as above.
This method hardly uses Pro/E's capabilities, but can usually be done faster than any other approach I have tried