Think there is some typo errors here:
"To prevent compressor second third stage discharge from overpressuring, the simple protective control loop PC400 shall be utilized. If compressor second third stage discharge pressure rises above the set point of the protective pressure controller PC400,then the pressure control valve on vent line opens. Setpoint of the protective controller PC400 shall be set higher than the setpoint of the controller PC225 PC200."
Re your query
"Why we select high selector?
If PC225 PV increases then controller output OP has to increase or decrease? And PC100A PC100B if Process value increases or decreases what will happen to output should be increases or decreases?"
Though your sketch is not complete, I can guess the following:
High selector is used because of the controller behavior selected. You can change to low select also, but controller behaviour then has to be changed.
In your case, if PC225 PV increases, then controller PC225 is DIRect acting and output will increase. For PC100B, if PV decreases, output is increasing - controller PC100B is REVerse acting. Then the output from high select PY225 is reversed and used to operate fail open PCV 225 on stage 2.
If you implement the changes I had suggested earlier, then PC100B and PC225 and PCV 225 can be deleted.
And all of this not required: " Compressor second stage discharge pressure is maintained by pressure controller PC225 .If compressor second stage discharge pressure rises above the set point of the pressure controller PC225,then the pressure control valves on 2nd stage spillback line open. The higher value of PC225 output and first stage protective pressure controller PC100B output is selected via High selector PY225.The purpose of the selector block is to prioritize compressor protection over delivering the hydrogen to the DHT Unit reaction section loop. Hydrogen delivery pressure to the DHT Unit".