As heard from a ASME Section IX committe member, Section IX is intended to be used with sound engineering judgment. Obviously, as you know the incoperation of every known metal would be irresponsible and dangerous. On the other hand, a PQR/WPS that would only be good for one heat of material would be rather restrictive. What I try to do is find relavent industry standards and see how a material not listed in Section IX is handled by other codes, such as D1.1, ASTM A488, MIL-STD-248, or other ones relavent to your industry. Just remember that Section IX is based on leak before break train of mind, so many materials that could be grouped together for qualification are not included because they aren't suitable for pressure vessels, (or piping for S No.s)