The answer depends on what you are trying to do. There are three types of magnetic couplings that I am aware of: Synchronous couplings, eddy-current couplings, hysteresis couplings.
Synchronous couplings involve two magnet assemblies arranged so that they spin together, without contact, at the same rate, up to a maximum level of torque.
Eddy-current couplings are used when the speed of one member needs to be held constant while the other member varies. Usually these involve a magnet assembly spinning relative to an electrical, non-ferromagnetic disc or ring.
Hysteresis couplings are used when one needs a predefined level of torque, irregardless of input speed. Usually these involve a magnet assembly spinning within a circumferentially oriented magnet ring.
If you are designing an eddy-current coupling, then adding a silicon steel ring will not help. It will work against the function of the device because it will be strongly attracted to the magnet.
Heat is an byproduct of eddy-current devices, there is no way to have eddy-currents without heat. The only option I can think of is to introduce some forced air cooling.