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constant enthalpy or entropy in PSV sizing?

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wormhhh

Chemical
Joined
Dec 22, 2005
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21
Location
US
Hi,there:

Would you handle the prossure relief process through the valve as an isenthalpy or an isentropy process? Please give some reference if possible. Same questions to control valve. Many thanks.
 
The gas is being throttled. The enthalpy is constant, but the internal energy is not necessarily constant. This may result in a temperature change through the valve. Look up information on the Joule-Thompson effect to better explain this.
 
Most of what I have read on the subject is to prefer treating it as an isentropic process although the isenthalpic approach is condidered acceptable. I think the isentropic process assumes all the energy of expansion goes into to kinetic energy. The isenthalpic process implies a some transfer of "expansion energy" to random heat. So, I would think that the isenthalpic process underpredicts the theoretical maximum flux.

The isentropic process, in theory, occurs in an ideal nozzle.
However, we generally assume that a gas expanding through an orifice in a pipeline is isenthalpic. PSVs seemed to be a combination of both.

 
Wormhhh,

I was involved with a similar discussion some time past. The discussion started about the outlet piping but also covers what happens in the PSV. Have a look at this thread...
thread408-63173

Hope this helps.
 
Everything I have ever seen on the topic indicates that the process is isenthalpic and essentially adiabatic.
 
thanks, guys. I appreciate it.
 
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