Your best bet is to add the impedance between the transformer neutral and ground. I'm not sure it is possible for the inherent zero sequence impedance to be greater than the positive sequence, at least in any practical transformer. The relationship between zero sequence impedance and positive sequence impedance in a delta-wye transforme is a by-product of the core design.
In a core-type transformer, the zero-sequence flux path typically must leave the iron. This reduces the inductance slightly.
To make the zero seq impedance higher, you would have to figure out a way to make the leakage reactance seen by zero sequence current greater than the leakage reactance seen by the positive seq current. I don't see how this can be done, but I'm not a transformer designer.
It should be quite simple to add a grounding resistor or reactor to the transformer to restrict ground fault current to whatever you desire. This is quite commonly done on medium voltage systems.
Hope this helps.
dpc