HiSet,
For a YN/yn configuration, with no tertiary winding, and the YN starpoint unearthed the zero sequence impedance will depend on the type of transformer construction. For shell type, the zero sequence impedance will be very high (some 100's %) and the earth fault current available on the LV side will be very low. For core type transformers, the zero sequence impedance will be around 50%, so you will get reasonable earth fault current. To answer your question, you can not just use the positive sequence impedance. If the HV starpoint was earthed then you could say that the zero sequence impedance was about the same as the positive sequence impedance.
There is an old book, but a very good one by Alvin H Knable "Electrical Power System Engineering", McGraw-Hill 1967 that discusses the subject well. A lot of texts make the statement that for a YN/yn transformer with ungrounded HV starpoint the zero sequence impedance is infinite and in this they are not correct. A number of electrical analysis software packages make the same assumption too.