The first question I would ask is, "what type of work do you do?"
Next question, "are you working to a specific welding code or standard such as AWS D1.1, API 1104, ASME B & PV Code, or military standards such as NAVSEA S9074-AR-GIB-010/278?"
Then, "what base metals are you welding?"
Based on your answers, you can decide what approach is applicable to your situation. There's no reason to qualify your welding procedures to ASME Section IX if your work is structural in nature and AWS D1.1 can be applied. Likewise, attempting to use prequalified WPSs based on one of AWS'structural welding codes are not applicable if you are working to NAVSEA S9074-AR-GIB-010/278 or ASME Pressure Piping Codes.
I see a lot of small contractors jump in with both feet before determining just what they are jumping into. You can waste a lot of time, effort, and money qualifying to the wrong welding standards.
AWS Structural Welding Codes - D1.1 carbon steel, D1.2 aluminum, D1.6 austenitic stainless steel, concrete reinforcing bars.
ASME Boilers, pressure vessels, pressure piping, all base metals (use Section IX as the basis of qualification)
API 1104 - petrochemical pipelines and equipment
NAVSEA - U.S. Navy ships and equipment, all base metals
Each of the organizations have different requirements for qualifying the welding procedures and the welders.
Good luck - Al