Aviation Gasoline Refining: Aviation FTR-3, Chapter 11, Chevron.
Avgas blending: [Aviation FTR-3, Chevron].
Aviation gasoline (avgas) is a highly refined product specifically manufactured to meet the demanding performance requirements of aircraft engines. Avgas specifications make it difficult to meet all the requirements with a single refinery stream, even one such as light alkylate produced specially for avgas. Avgas, like motor gasoline (mogas) and most other refinery products, is usually produced by blending two or more components to achieve the desired properties. [FTR-3, p.65, Chevron].
In 1930, the US Army Air Corps specified a ‘Fighting Grade’ avgas with a minimum octane number of 87. This is believed to be the first instance in which the antiknock properties of avgas were defined in terms of octane numbers. By the start of WWII, avgas very similar to today’s Grade 100 were in use. Avgas reached its development peak during WWII and the following decade. In 1944, the US military issued a specification for Grade 115/145. This fuel, which had the highest antiknock rating (performance number) of any avgas in large-scale production, was used to obtain maximum output from military high-performance aviation engines. Currently, ASTM (ASTM D 910) specifies three grades of avgas: Grades 80, 100 and 100LL (low lead). The ASTM has recently (2003) approved a new specification for a low octane unleaded avgas, Grade 82UL. Grades of avgas are identified by their nominal minimum lean mixture anti-knock rating. Historically, (until the 1970s) both the lean and rich mixture ratings were used, now only the lean mixture rating (octane number) is used. [FTR-3, p.41]. In practice, only 100LL is widely available. Grade 80 continues to be marketed but its distribution and availability is much more limited. Grade 100 is now rarely found. With continuing modernization of the aircraft fleet over time, the demand for Grade 80 continues to decline. It is expected that it will eventually reach a point when it is no longer economical to manufacture or use. Today avgas is used mainly by small aircraft and light helicopters; there is still a small but significant number of military and civilian transports that still use avgas.
The ASTM D 910 specification defines three grades of avgas, with names based on their antiknock quality as measured by Octane numbers. The grades are 80, 100, and 100LL, all of which contain tetraethyl lead (TEL).
Grades 100 and 100LL avgas are based on alkylate. As such, they are mainly synthetic products. Grades 100 and 100LL represent avgas identical in antiknock quality, but differing in maximum lead content. The lower lead content avgas, (100LL), is suitable for modern engines having a low tolerance to TEL. Few of the compounds in avgas come directly from crude oil. Toluene is often added to Grade 100LL to help meet the rich-mixture antiknock requirement. Because of the lower antiknock requirement of Grade 80 avgas, it may contain some straight-run gasoline distillate that has been subjected to additional purification after distillation. Light hydrocarbons, such as butane or isopentane are added to all grades to meet the minimum vapor pressure requirement. (Avgas must have vapor pressure of between 5.5 and 7.0 psi). Finally, additives are added: the required concentration of the appropriate tetraethyl lead (TEL)/ethylene dibromide (EDB)/dye mixture and any of the optional additives the manufacturer chooses to use [FTR-3, p. 65.1, Chevron]. Additives are hydrocarbon-based chemicals added to avgas in small amounts to maintain or enhance properties of performance or handling. Only additives approved by ASTM D 910 may be used in avgas. Approved additives are identified by their chemical formulas. For avgas Grades 80, 100 and 100LL, TEL, EDB and dye are mandatory.
Although the grade designations show only a single octane rating, antiknock quality is expressed by two values; the lean mixture motor rating and the rich mixture supercharge rating. The lean mixture rating is intended to simulate the lean air/fuel mixture of cruise conditions, and the rich rating simulates takeoff under rich mixture supercharge conditions.