MintJulep is correct; train brakes are not spring applied, but they act as if they were, sort of.
More detail:
Every car, or at least one car of every set of cars, has an air reservoir, a special valve, and a pipe connecting to the next car at each end by a hose.
The pipes are all connected together, and together form the 'train air line'.
From startup, the locomotive's air compressor feeds the train air line, which charges each reservoir. The special valve, first invented by George Westinghouse, applies the brakes, using whatever pressure is in the reservoir, and keeps them applied until the train air line pressure reaches some minimum, which ISTR is around 90 psig. As the train air line pressure rises above that level, the valve releases the brakes.
... So the engineer reduces the train air line pressure a little to apply the brakes. If a coupling separates, intentionally or not, the brakes are applied and held until the train air line pressure comes up again to release them, all by the special valve.
Because the reservoirs and valves are not perfect, the cars are also equipped with manual operators for the brakes, and the wheels are chocked when parking a train.
Mike Halloran
Pembroke Pines, FL, USA