I believe xcrosby is correct regarding a Class 600 originally being suitable for saturated steam at 600 psi (which has a temperature of around 1100 °F I think).
I am not sure what xcrosby meant by "As materials improved the actual pressure ratings increased but the class designation remained.".
ANSI flange tables have a whole host of materials, and temperature/pressure relationships. Different materials, of course have different temperature/pressure relationships - not so much better/worse, just different.
Also keep in mind, the ANSI flange tables by class has taken into account that different pressure class flanges are constructed differently (eg 300# flanges are much more stout, have more material, than 150# flanges, and different bolting patterns too).
"Do not worry about your problems with mathematics, I assure you mine are far greater."
Albert Einstein
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