Compositepro's observation about not going into a vacuum is a good one. This would limit the design temperature to -28F. However, ammonia will operate with reasonably good efficiency down to -40F. A good purger takes care of the air. Ammonia vapor volume increases drastically as the temperature is lowered further. mtngreen's comment that -60F is about as cold as one can reasonably achieve is also accurate, but even there higher pressure refrigerants than ammonia should be considered.
NXTCOLD