The electrical power utility I used to work for did it thusly, if I remember correctly:
2300- 13,800: Low voltage
20,000 - 69,000: Medium voltage
138 - 230 kV: High voltage
500 kV: Extra high voltage.
Many of the local industries make the divide their in-plant systems thusly:
<600 volts: Low voltage
2300 - 4160: medium voltage
13,200, 13,800: high voltage
Most of the local heavy commercials define it as:
<300: Low voltage (120, 208, 240, 277)
480: High voltage
>480: call a contractor
old field guy