osuamp
I would guess the problem you have here is not due to materials but the valve design itself. With the advent of changing plant operating philosophies, valves are now heated up and cooled down far more frequently and quickly than previously. This leads to a significant thermal gradient across the crotch area of a Parallel slide valve,(or Wedge gate) often resulting in cracking across the seating area. F91 was meant to overcome this problem as it allowed much thinner sections in this area due to its improved mechanical properties at elevated temperature. Unfortunately many valve companies have copied designs over the years and have not understood the differences between say a WC9 design and an F91 design. They just simply change materials and end up with the same problem.
I believe this is where your problem lies. Try speaking to a UK manufacturer who have modified their designs to suit, Hopkinsons or Dewrance would be a good bet.